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AQA Chemistry


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[Front]


What is are all substances made off
[Back]


atoms

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AQA Chemistry - Details

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What is an element
Contains only one type of atom e.g. Mg, S, K
What is a compound
Two or more different elements that are chemically combined
What is an atom
The smallest possible unit of an element
What is a mixture
Different elements or compounds that are not chemically combined
How do we separate a mixture
Using physical techniques
What are examples of a physical technique
Filtration, distilation, chromatogrpahy etc
What is a molecule
Any element chemically joined
MgS
1 atom of magnesium 1 atom of Sulphur
Na2SO4
2 atoms of sodium 1atom of Sulphur 4 atoms of Oxygen
Name all the key features of a chemical reaction
1) compounds are broken up or formed 2)at least one new substance is created 3) no atoms are created or destroyed 4)measurable energy change
What happens to the chemical properties of a mixture
Doesn't change because they have been mixed with another substance
Give me two examples of a mixture
1) Air (mix of oxygen-nitrogen and co2 2) A bowl with pasta and vegetables
What is filtration
Separates an insoluble solid in a liquid
What does insoluble mean
The solid wont dissolve in a liquid
How do we filter an insoluble solid
We need a filter funnel and filter paper 1)Pour the mixture into the filter paper The liquid passes through while the solid is trapped
What is crystalisation
Separate a soluble solid from a liquid
Give me a benefit of evaporation
Quick and easy to separate the soluble solid from liquid
Give me a disadvantage of evaporation
Some solids decompose when heated(thermal decomposition)
How do we use evaporation to separate a soluble solid from a liquid
1) Pour mixture into an evaporating dish 2) place on top of the tripod 3) Then slowly heat with bunsen burner This cause the solvent to start evaporating and the solution to become more concentrated forming crystals
How do we use crystallization to separate a soluble solid from a liquid
1) Pour mixture into an evaporating dish 2) Heat with a water bath Once we see crystals start to form we stop heating it and take out the water bath and let it cool 3) Then filter and dry
Why do we leave it out to cool
Because solids are less soluble at colder temp
Steps of crystalisation
1) Gently heat the mixture till the solvent evaporates 2) Crystals of the solid will start to form
What was Thomsons plum pudding model
- discovered electrons in 1897 - a ball of positive charge with electrons mixed in with the dough
What was Rutherfords nuclear model
- discorved an atoms mass is concentrated in centre - and contained protons
What was Niels Bohr discorvery
- electrons orbit the nucleus - some particles have no charge and he called it neutrons
Charge of sub atomic particles
Protons - +1 (mass of 1) electrons - -1(mass very small) neutrons - 0 (mass of 1)
What is simple disilation
Separates out a liquid from a solution and also 2 liquids with different boiling points
How does it work
1)Place the solution into the flask 2)Heat the solution which causes the liquid to evaporate turning into a vapor 3)The vapor rises up the glass tube 4)The vapor then passes into the condenser where it turns back to a liquid 5)Collect the liquid in a beaker so at the end we're left with a solid in the flask and liquid in the beaker
Why is a thermometer used in simple distillation?
To make sure that the highest boiling point isnt exceeded otherwise both liquids would boil and wouldnt be seperated
What is fractional distillation used for
Separte a mixture of different liquids with different boiling points
Describe a method for making pure crystals of magnesium chloride from magnesium and dilute hydrochloric acid.
1) Add a fixed volume of hydrochloric acid to the beaker 2) add small pieces of magnesium ribbon until its in excess so all the acid as reacted 3) filter out any excess magnesium using filter paper and funnel 4) add solution to an evaporating basin 5) heat with a bunsen burner until it starts to crytsalise 6) pat dry the crystals on paper towels
What are hydrocarbons
Molecules containing hydrogen and carbon atom only
How is crude oil formed
From the remains of fossiled planktons
What is crude oil used for
To produce fuels and other useful chemicals
What is crude oil a mixture off
Lots of different compounds that are not chemically combined
Why do heavy fractions of crude oil not make good fuels
1) Low volatility 2) Don't ignite easily 3) Have high boiling points
What are the bonds of carbon in alkanes
Carbon atoms bond to four other atoms(either hydrogen or carbon)
Why are alkanes called saturated
Because they only contain a single bond with other atoms
What are alkanes used for
They're quiet unreactive but can burn well so they make good fuels
Name the 4 smallest hydrocarbons in order
1) Methane 2) Ethane 3) Propane 4) Butane
Give me the properties of Longer chained hydrocarbons
- Higher viscosity(flow less easily) - Less flammable - Higher boiling point
Give me the properties of a short chained hydrocarbon
- Highly volatile - Ignite easily - Low boiling points
What is fractional distillation
Process of separating crude oil into fractions
Describe the process of FD
1) Crude oil is evaporated - the vapors are put into the fractionating column at the bottom and raises upwards 2) Long chained HC condense at the bottom due to the high BP - SC HC condense nearer to the top due to it being highly volatile 3) The fractions are collected then processed to create products (petrol, diesel, etc)
What is cracking
Breaks down longer chained hydrocarbons into smaller more useful molecules
Steps to catalytic cracking
- Vapourised hydrocarbons passed over hot catalyst - The product includes alkanes and alkenes
Steps to steam cracking
- Vapourised HC mixed with steam at high temp - Products include alkanes and alkenes
Name the uses of alkenes
- combined to make polymers - starting material for chemicals like ethanol
What is a pure substance
Single element or compound
How do we work out purity
- By looking at melting and boiling points of samples - pure have exact and specific melting and boiling points
What are some examples of pure substances
Water, glucose, oxygen, sodium chloride etc
Impurities effect on melting point
Lower melting point Increase range of temp that the sample will melt
Impurities effect on boiling point
- increase boiling point - increase range of temp at which sample will boil
What is a formulation
Mixtures of chemicals that are designed to create more useful products
Quantity of each component in a formulation
To ensure that the formulation does its job, each component must be present in a precisely measured quantity
Give me an example of a formulation
Metal alloys, medicines and fertilisers
Pure substances on melting and boiling
Only pure substances melt and boil at specific temperatures
What does water boil at
100 degrees celcius
What is aa physical test
Testing the ohysucal proepeties of a substance
Impure substances on melting and boiling
They melt and boil over a range of temperatures depending on how much of each substance is in the mixture
What is chromatography
Separates mixtures into its different components
Impurities on melting and boiling point
- lower melting point - increase boiling point
What are the two phases of chromatography
Phase 1 - Substances picked up and carried by a mobile phase(liquid or gas) phase 2 - Mobile phase moves into a stationary phase (solid or viscous liquid)
Quantity of each component in a formulation
Each chemical component must be measured in precise quantity to ensure that the formulation works
Equation for Rf value
Distance travelled by substance/ distance travelled by solvent
What is chromatography
Analytic technique used to separate different substances from mixtures
Paper chromatography experiment
1) Take filter paper and draw a line near the bottom(baseline) 2) Add a sample of ink to the pencil line 3) Add a shallow amount of solvent to the beaker 4) Then place filter paper into solvent but make sure it doesn't submerge the pencil line 5) Wait for the solvent to seep up the paper, then the different dies which make up ink will dissolve and rise with it 6) Take out the paper and leave it to dry
How does each die travel
At different rates - each one must be a different substance
What is the mobile phase
Substances the molecules can move in e.g. liquid or gas
What is the stationary phase
Substance the molecules cant move in e.g. viscous liquid or solid
Chemicals more soluble in solvent
Spend more time in mobile phase therefore moving faster
Chemicals less soluble
Spend more time in stationary phase therefore moving more slowly
What is a reference substance
A pure sample that runs alongside the unknown mixture to see if its a component in the mixture
How do we test for Hydrogen
- Hold a lit splint at the end of a test tube containing a gas - If its hydrogen a squeaky pop will be let off
How do we test for oxygen
- Insert glowing splint into test tube containing a gas - If gas is oxygen the splint will relight
Testing for carbon dioxide
- shake carbon dioxide with calcium hydroxide - The solution will turn from clear to cloudy
Testing for chlorine
- damp litmus paper into test tube containing a gas - If the gas is chlorine the litmus paper will change from red to white
What do elements in the same column have in common
Same amount of electrons in the outer shell
Predicting chemical properties
Because elements in the column have same number of electrons in their outer shell, they have similar chemical properties and will react in similar ways